Black-Body Radiation and Quantum Theory
Black-body radiation curves, Wien’s displacement law λ_max T = b, Stefan-Boltzmann law E = σT⁴, classical failure (ultraviolet catastrophe), and Planck’s quantum hypothesis E = nhf.
Marking a lesson complete represents finishing your study of the topic; it does not denote tested mastery.
Learning Objectives
- Explain the spectral distribution of black-body radiation and apply Wien’s displacement law and the Stefan-Boltzmann law.
- Describe how Planck’s quantization hypothesis resolved the ultraviolet catastrophe and initiated modern quantum physics.
Core Theory & Concepts
A black body absorbs all incident electromagnetic radiation regardless of frequency or angle of incidence. The spectral distribution of its emitted radiation at thermodynamic temperature T could not be explained by 19th-century classical electromagnetism, compelling Max Planck in 1900 to introduce energy quantization.
Wien’s Displacement Law
The wavelength of peak emissive power λ_max is inversely proportional to absolute thermodynamic temperature T: λ_max T = b, where Wien constant b ≈ 2.898 × 10⁻³ m K.
Stefan-Boltzmann Law
The total energy radiated per unit surface area per second across all wavelengths is proportional to the fourth power of absolute temperature: E = σ T⁴, where σ = 5.670 × 10⁻⁸ W m⁻² K⁻⁴.
Planck’s Quantum Hypothesis
Atomic oscillators in cavity walls can only absorb or radiate thermal energy in discrete bundles (quanta): E = n h f, where n = 1, 2, 3... and h = 6.626 × 10⁻³⁴ J s.
Common Misconceptions
As a black body gets hotter, its peak radiation wavelength shifts toward longer wavelengths (red).
Syllabus Topic Outline
- 1Concept of a perfect black body and experimental cavity radiator
- 2Spectral energy distribution curves at different temperatures
- 3Wien’s displacement law: λ_max T = constant (2.898 × 10⁻³ m K)
- 4Stefan-Boltzmann law: total emissive power E = σ T⁴
- 5Rayleigh-Jeans law failure and the Ultraviolet Catastrophe
- 6Max Planck’s quantum hypothesis: discrete energy packets E = hf